This is "The Anxious Journey" by Giorgio de Churico. This was painted in 1913 and the medium is oil on canvas. "The Anxious Journey" is on display at the Museum of Modern Art in New York City.
The reason why I chose this painting was because it gave me anxiety before I was aware of the title. Also, I liked de Churico's use of value in this photo. It is very mysterious. In one of the window openings is a random train coming toward the building. This makes my anxiety rise.